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Abstract
We continue the study begun in [1, 2] of chemical processes in perchloric acid—ammonia flames. We propose new channels for the reaction. Based on experimental data on the chemical structure of an ammonium perchlorate flame and flames in O2/NH3/Ar, NH3/HClO4/H2O/Ar mixtures, we estimate the rate constants for steps that have not been well studied and refine the kinetic mechanism of [1, 2]. We discuss calculation results for the chemical structure of a flame in an NH3/HClO4/H2O/Ar mixture and an ammonium perchlorate flame. We simplify the kinetic mechanism.
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