Abstract
TEMPO-based spin probes and beta-cyclodextrin form 1 ratio 2 guest-host complexes in viscous aqueous glycerol solutions at low temperatures. The spin probe mobility in these complexes is much higher than in the bulk glassy solution. The similar tumbling rates of the spin probe in viscous host-guest complexes and in solvent-free complexes suggest that the complexation effectively shields the nitroxide unit from the solvent molecules. This is consistent with the low activation barrier for molecular tumbling of immobilised label.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
