Mobility of copper, chromium and arsenic from treated timber into grapevines

Abstract

The use of chromated copper arsenate (CCA) treated timber posts as support structures in New Zealand vineyards has raised concerns regarding the release of heavy metal(loid)s from the treated timber into the environment. A laboratory experiment was set up to evaluate if post sealing by painting reduces the release rate of CCA metal(loid)s from timber posts. Three posts were painted (Gripset 38, Multi Purpose Bitumen Rubber) on the bottom part, submerged in freshwater, and the concentrations of copper (Cu), chromium (Cr) and arsenic (As) in the water were monitored over a period of 8 months. Three additional, unpainted posts were also used. The CCA contents in the water showed a clear difference between the painted and the unpainted posts, and painting the bottom of the posts reduced the release rate by 50–75%. To monitor the possible mobility of CCA from treated posts into grapevines further, an experiment with four-year-old grapevines planted into sixteen lysimeters was set up in a greenhouse. To half the lysimeters Cu, Cr and As were added to the soil surface at rates of 16, 20, and 12.5 mg/month from 15 November 2005 to 5 May 2006. The other lysimeters acted as a control. Soil solutions were collected at 50, 150 and 300 mm depths using suction cups after seven application of the CCA solution. The results showed that all the elements moved to a depth of 50 mm. Grape fruit, leaves and rachis were analysed for CCA metal(loid)s, but did not show any differences between the CCA-treated and control lysimeters. This indicated either that these metals were not taken up by grapevines or that their translocation from roots to the upper part of the vine was negligible. Further monitoring of CCA metal(loid)s in various parts of the grapevines, including roots, needs to be undertaken.