Abstract

Mo-based layered nanostructures are two-dimensional (2D) nanomaterials with outstanding characteristics and very promising electrochemical properties. These materials comprise nanosheets of molybdenum (Mo) oxides (MoO2 and MoO3), dichalcogenides (MoS2, MoSe2, MoTe2), and carbides (MoC2), which find application in electrochemical devices for energy storage and generation. In this feature paper, we present the most relevant characteristics of such Mo-based layered compounds and their use as electrode materials in electrochemical sensors. In particular, the aspects related to synthesis methods, structural and electronic characteristics, and the relevant electrochemical properties, together with applications in the specific field of electrochemical biomolecule sensing, are reviewed. The main features, along with the current status, trends, and potentialities for biomedical sensing applications, are described, highlighting the peculiar properties of Mo-based 2D-nanomaterials in this field.

Highlights

  • Nanotechnologies have enabled the manipulation of materials on a nanoscale, giving birth to new products with novel characteristics and properties

  • Due to the strong interest, in this feature paper we review the various aspects of these layered to the strong interest, in this feature paper we review the various aspects of these layered materials Due ranging from synthesis methods, and structural and electronic characteristics to the relevant materials ranging from synthesis methods, and structural and electronic characteristics to the electrochemical properties in the specific field of electrochemical biomolecule sensing

  • In the last few years, electrochemical sensors have gained the interest of researchers for the detection of biomolecules, i.e., substances having a key role in the biochemical processes of living systems

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Summary

Introduction

Nanotechnologies have enabled the manipulation of materials on a nanoscale, giving birth to new products with novel characteristics and properties. 2D nanomaterials have single or multiple layers with strong in-plane and weak out-plane bonding as atomically ordered networks The combination of these microstructural characteristics confers on them, among other things, large adsorption capacity and strong surface reactivity, causing a big enhancement in their electrical, catalytic, and electrocatalytic properties with respect to bulk materials. The two-dimensional electron confinement of ultra-thin 2D nanomaterials, leads to very interesting electrical properties compared to other nanostructures with different morphologies All of these significant properties make the use of 2D materials the best choice in various fields such as sensing, energy-storage, drug carriers, diseases treatment, diagnosis, and therapy [4,5,6,7,8], which are expected to cause an enormous impact on human life within the near future. The developed devices show great potential, because their sensing characteristics can be modulated by the proper use of layered nanomaterials based on different inorganic elements [15,16,17].

Mo-Based
Hybrid Structures
Synthesis Methods of Mo-Based 2D Layered Materials
Atomic
Chemical Etching
Hydrothermal Synthesis
Exfoliation
Miscellaneous Synthesis
Voltammetry
Mo-Based 2D Layered Materials for Electrochemical Biomolecules Sensing
Hydrogen Peroxide
Glucose
Neurotransmitters
Vitamins
Other Biomolecules
Other biomolecules
Current and Future Perspectives
Conclusions

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