MnO₂ Nanoparticles Anchored Multi Walled Carbon Nanotubes as Potential Anode Materials for Lithium Ion Batteries.

Abstract

Herein, we report a facile hydrothermal synthesis of MnO₂ nanoparticles anchored multi walled carbon nanotubes (MnO₂@MWCNTs) as potential anode materials for lithium-ion (Li-ion) batteries. The prepared MnO₂@MWCNTs were characterized by several techniques which confirmed the formation of MnO₂ nanoparticles anchored MWCNTs. The X-ray diffraction and Raman-scattering analyses of the prepared material further revealed the effective synthesis of MnO₂@MWCNTs. The fabricated Li-ion battery based on MnO₂@MWCNTs exhibited a reversible capacity of ~823 mAhg-1 at a current density of 100 mAg-1 for the first cycle, and delivered a capacity of ~421 mAhg-1 for the 60 cycles. The coulombic efficiency was found to be ~100% which showed excellent reversible charge-discharge behavior. The outstanding performance of the MnO₂@MWCNTs anode for the Li-ion battery can be attributed to the distinctive morphology of the MnO₂ nanoparticles anchored MWCNTs that facilitated the fast transport of lithium ions and electrons and accommodated a broad volume change during the cycles of charge/discharge.