Abstract

A noticeable improvement in the structural properties of Mn–Zn ferrite obtained by the solution combustion method was observed when the gel was additionally dried before self-combustion. The catalytic activity of thus prepared nanosized Mn–Zn ferrite has been also studied. The powders after combustion process were analyzed by X-ray diffraction and it was found that they possess pure spinel phase. The ferrite particles were agglomerated wherein powders obtained from the modified solution combustion method (gel additionally dried) characterized sponge-like structure and developed specific surface area. This ferrite material exhibits a significantly higher total acidity and it is reduced in the lower temperature. As a ferrite catalyst, prepared by the modified solution combustion method, possesses both acid and base centers, which allows to proceed the bimolecular ketonization reaction. The yield and selectivity of ketone increase with temperature with a maximum at 440 °C. Taking into account the obtained yield and selectivity results in the butan-1-ol conversion the Mn0.6Zn0.4Fe2O4 ferrite prepared in low temperature can be used as potential dehydrogenation catalyst.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.