Abstract

Continuous ultrasonic in-situ monitoring for industrial applications is difficult owing to the high operating temperatures in industrial fields. It is expected that ultrasonic transducers consisting of a CaBi4Ti4O15(CBT)/Pb(Zr,Ti)O3(PZT) sol-gel composite could be one solution for ultrasonic nondestructive testing (NDT) above 500 °C because no couplant is required and CBT has a high Curie temperature. To verify the high temperature durability, CBT/PZT sol-gel composite films were fabricated on titanium substrates by spray coating, and the CBT/PZT samples were tested in a furnace at various temperatures. Reflected echoes with a high signal-to-noise ratio were observed up to 600 °C. A thermal cycle test was conducted from room temperature to 600 °C, and no significant deterioration was found after the second thermal cycle. To investigate the long-term high-temperature durability, a CBT/PZT ultrasonic transducer was tested in the furnace at 600 °C for 36 h. Ultrasonic responses were recorded every 3 h, and the sensitivity and signal-to-noise ratio were stable throughout the experiment.

Highlights

  • Ultrasonic monitoring at elevated temperatures is desired in industrial fields because it can detect failure phenomena such as thickness reduction, corrosion cracks, micro-void generation, and processed material deterioration in an early stage [1,2,3]

  • Air-coupled ultrasonic transducers have good acoustic impedance matching with air; it is suitable for the nondestructive testing (NDT) of light materials such as graphite composites but not for the NDT of metals, which are the main targets of high-temperature ultrasonic NDT

  • CaBi4 Ti4 O15 (CBT)/PZT films were fabricated on titanium substrates with a 3 ± 0.2 mm thickness, a 30 ± 1 mm length, and a 30 ± 1 mm width

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Summary

Introduction

Ultrasonic monitoring at elevated temperatures is desired in industrial fields because it can detect failure phenomena such as thickness reduction, corrosion cracks, micro-void generation, and processed material deterioration in an early stage [1,2,3]. Even though ultrasonic nondestructive testing (NDT) is one of the common NDT techniques [4], long-term high-temperature application of ultrasonic NDT is difficult. For the general ultrasonic transducer using the contact method, an acoustic couplant to transmit ultrasound into test objects and a backing material to achieve a broad frequency bandwidth are used [5]. These materials cannot withstand elevated temperatures in the long term. Air-coupled ultrasonic transducers have good acoustic impedance matching with air; it is suitable for the NDT of light materials such as graphite composites but not for the NDT of metals, which are the main targets of high-temperature ultrasonic NDT. The use of a delay line is another method to avoid the direct contact of the ultrasonic measurement system with high temperatures [8], though the measurement system becomes bulky

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