Abstract
Aluminum hydrolysis in mixed liquid reactors is a problem with multiple kinetic and mixing time scales. Since some of these times scales overlap, and since aluminum hydrolysis has multiple pathways (some of which are slowly reversed), we have modeled aluminum precipitation as a coupled mixing and chemistry problem. For the base neutralization of dilute aluminum chloride in a standard stirred reactor with Rushton impeller, mixing submodels are combined with simplified aluminum chemistry models to predict the effect of mixing on steady-state pH at various formation or neutralization ratios
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