Abstract
A one-dimensional (1D) inorganic–organic hybrid based on sandwich-type copper(I)-iodide nanochain was synthesized for the first time. By replacing the copper(I) ions at the sandwich layer with silver(I) ions, a Cu(I)-Ag(I) bimetallic iodide nanochain was isolated. Although they are isostructural, the mixed-metallic one shows a larger band gap and stronger photoluminescence compared with the homometallic one, which may be contributed to the changed valence bands and metallophilic interactions modulated by the silver ions.
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