Abstract
Abstract Mixed-valence states of 57Fe atoms produced by EC-decay in 57Co-labelled [CoFe2O(CH2ICO2)6(H2O)3] and [CoFe2O(CH2BrCO2)6(H2O)3] were studied by means of emission Mössbauer spectroscopy. It was found that [CoFe2O(CH2ICO2)6(H2O)3] and [CoFe2O(CH2BrCO2)6(H2O)3] show a temperature-dependent trapped-to-averaged valence state and a temperature-independent trapped-valence state, respectively.
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