Abstract
A set of new mixed valence complexes of the type Na 3[(edtaH)Ru IIILFe II(CN) 5], where L pyz, bp, dmbp, etybp or tmbp, has been synthesized and characterized by physico-chemical methods. The kinetics of formation of these binuclear complexes were studied using a stopped-flow spectrophotometer. Electrochemical studies for these complexes show only a weak metal-metal interaction in the ground state. All these complexes, except the one incorporating tmbp, gave an MMCT band in the region 900 > λ > 1000 nm and belong to the Robin-Day class II type.
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