Abstract

Partition coefficients of n-alkanes and other substances were measured at 393 K on mixed stationary phase columns prepared by mixing OV-101 with OV-25, OV-101 with Carbowax 20M and OV-225 with SP-2340. The results are examined with respect to the Purnell—Vargas de Andrade and Perry—Tiley relationships. The solvent—solvent interaction parameter was calculated in the three systems. When the value of this parameter is higher than 2 a clear departure from the linear approximation was observed. Retention indices were also calculated and compared with those predicted by the above relationships.

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