Abstract
Abstract A film balance study of the mixed monolayers with various ratios of poly(methyl acrylate) and its saponified polymer or of the monolayers themselves was carried out on distilled water, and the mixed monolayers were compared with individual monolayers of the saponified polymers. These mixed monolayers expanded more than individual saponified polymers at the same degree of saponification, giving larger limiting areas. Their limiting areas deviated from the linearity between the limiting area and the degree of saponification, in contrast to the fact that the limiting areas of individual monolayers decreased linearly with an increase in the degree of saponification. This fact can be considered to be due to interactions between the side chains of the ploymers.
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