Abstract
The results from a systematic synthesis and trends in structural and physical properties and chemical reactivity for a large group of clusters are valuable for the understanding of the role of a particular element in a mixed metal cluster. As an example tetrahedral H x M 4(CO) 12 clusters, where M represents metals Fe, Ru, Co and Rh or their combinations, are discussed in detail. Their metalmetal bond distances and 1H NMR parameters are presented as a function of metal composition. Similar trends are also shown for their reactivity towards phosphine substitution.
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