Mixed matrix membranes applications: Development of a resistance-based model

Abstract

In this study, a model for the prediction of the mass transport through ideal mixed matrix membranes (MMMs) for pervaporation and gas separation processes has been introduced. A Resistance-Based (RB) model was used in conjunction with a three-directional Finite Difference (FD) numerical solution to derive a semi-empirical model for calculating the effective permeability of ideal mixed matrix membranes. Predictions of the effective permeability obtained with the proposed model were compared with the estimated permeability for ideal MMMs using numerous analytical solutions such as Maxwell, Lewis-Nielsen, Bruggeman and Hennepe models. The extended RB model was theoretically able to predict accurately the effective permeability of ideal MMMs over a large range of filler volume fraction. Higher deviations were observed between the predictions of the extended RB model and the estimations of the majority of the other models in the case of MMMs containing higher permeable fillers and larger amount of filler material.