Abstract

AbstractChemical diffusion in mixed ionic electronic conductors (MIECs) occurs via ambipolar motion. It finds many applications which are reviewed. The partial ionic and electronic conductivities are also of interest. Methods for determining these quantities are reviewed emphasizing problems with the Hebb-Wagner polarization method and suggesting an alternative method. The use of MIECs for probing simultaneously the ionic and electronic driving forces and for producing p-n junctions is discussed.

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