Abstract
1. Circular dichroism, electronic spectra, and PMR methods have been used to study the formation of mixed complexes through the reaction of tris(triphenylphosphine)rhodium(I) chloride with d-α-methylbenzylamine. 2. Working in Ar or H2, only one triphenylphosphine molecule is substituted by an amine in these complexes. 3. A kinetic scheme showing formation of a catalytically active solvated complex through predominant elimination of the coordinated amine molecule has been proposed to account for mixed complex catalysis.
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