Abstract
1. Mercury salts of carboxylic acids are readily added on to bis(trifluoromethyl) ketene and its N-phenylimine, forming mixed anhydrides or imides of α-mercuriobishexafluoroisobutyric acid. 2. The mixed anhydride of trifluoroacetic and α-mercuriobishexafluoroisobutyric acids is readily decomposed to bis(trifluoromethyl) ketene, trifluoroacetic anhydride, and the internal salt of α-mercuriohexafluoroisobutyric acid. On decarboxylation in pyridine this salt is converted to hexafluoroisopropylidenemercury.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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