Abstract

Lightweighting has become an important factor in the automotive industry due to stringent government regulations on fuel consumption and increased environmental awareness. Aluminum alloys are 65% lighter than cast iron enabling significant weight reduction. However, there are several significant challenges associated to the use of hypoeutectic Al-Si alloys in engine block applications. This dissertation investigated the factors influencing the susceptibility of in-service cylinder distortion as it is deleterious to engine operating efficiency, leading to environmental (increased carbon emissions) and economic (expensive recalls) repercussions. The initial segment of this dissertation sought to quantitatively confirm the cause of cylinder distortion by investigating distorted and undistorted service tested engine blocks. This analysis involved measurement of macro-distortion using a co-ordinate measuring machine, in-depth microstructural analysis, measurement of tensile properties, and residual stress mapping along the length of the cylinder bores (neutron diffraction). Upon determining the cause of distortion, the second phase of this project optimized the solution heat treatment parameters to mitigate future distortion in the engine blocks. This optimization was carried out by varying heat treatment parameters to maximize engine block strength. In addition, a pioneering application of in-situ neutron diffraction, along with a unique engine heating system, was used to develop a time-dependent correlation of residual stress relief during heat treatment, assisting in process optimization. The results indicate that the distorted engine block had high tensile residual stress, specifically at cylinder depths greater than 30 mm, while the undistorted block had mainly compressive stress. The maximum distortion occurred near the center portion of the cylinder (~60 mm), which had a combination of coarse microstructure (lower strength) and high tensile residual stress. As such,distortion can be prevented via maximization of strength and reduction in tensile residual stress. Lab scale castings and in-situ neutron diffraction were used to successfully develop an optimal heat treatment process to increase engine block integrity. These experiments found that solution heat treatment at 500 °C for 2 h increased tensile yield strength by 15-20% over engines produced using the current process. Furthermore, tensile residual stress was completely relieved by this heat treatment, reducing the susceptibility to in-service distortion. Solutionizing at temperatures above 500 °C was deemed unsuitable for engine block production due to incipient melting, which deteriorates strength.

Highlights

  • Lightweighting has become an important factor in the automotive industry due to stringent government regulations on fuel consumption and increased environmental awareness

  • Colley et al [42] found that this phase is only soluble when solutionized at 505 oC, with higher temperatures resulting in localized melting. This observation supports the CALPHAD calculations carried out by Chaudhury et al [37], which indicated that complete dissolution of Cu and Mg bearing phases occurs at temperatures between 505 and 515 oC for 319 Al alloys containing less than 0.48 wt.% Mg

  • This study illustrated that relief of residual stress during heat treatment was accomplished by instantaneous relaxation and by time-dependant creep, while other previous studies only show the creep portion since the temporal resolution was not sufficient to capture stress relief during heat-up

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Summary

Chapter 1: Introduction

Development of light weight powertrain components utilizing low density aluminum (Al) alloys (2.7 g/cm3) have increasingly replaced ferrous materials such as steels and cast irons (7.8 g/cm3) [1] in order to meet both consumer demand for more fuel efficient vehicles and stricter government legislation on emissions. In typical Al engine blocks, gray iron cylinder liners, inserted to mitigate the poor wear resistance properties of hypoeutectic Al-Si alloys, cause the development of large tensile residual stresses along the cylinder bore region, due to the difference in thermal expansion coefficient between these dissimilar materials. To improve the integrity of the cast engine block and mitigate potential problems (loss of efficiency, increased emissions and recall costs) for the automotive industry, there is a need to develop a scientific explanation for the cause of cylinder distortion and optimize the heat treatment parameters in order to prevent its formation as well as reduce part manufacturing costs. The objective of this dissertation is to extend the understanding on the relationship between process variables (casting and heat treatment parameters), microstructure, mechanical properties and residual stress with a view to connecting these with the occurrence of macro-distortion This will enable the effective development and implementation of preventative measures.

Chapter 2: Literature Review
Microstructure of Aluminum-Silicon-Copper (319) Alloy System
Al-Si Eutectic
Al2Cu and Al5Mg8Cu2Si6 The addition of
Fe-bearing Intermetallics Most commercial
Heat Treatment of 319 Aluminum Alloys
Solution Heat Treatment
Eutectic Si Morphology
Effect of Particle Size on Secondary Phase Dissolution
Effect of Particle Morphology on Secondary Phase Dissolution
Incipient Melting of Secondary Phases
Artificial Aging
Precipitation Sequence during Aging
4.05 Å (pure Al lattice)
Effect of Heat Treatment Condition on Mechanical Properties
Effect of Heat Treatment Condition on Dimensional Stability
Residual Stress
Thermal Gradients
Thermo-Mechanical Mismatch
Mechanisms of Residual Stress Relaxation
Residual Stress Relief in Aluminum Engine Blocks
Chapter 3: Experimental Methodology
Analysis of the Mechanism of Cylinder Distortion
Current Engine Block Production Parameters
Measurement of Cylinder Distortion
Microstructural Analysis
Sample Preparation for OM and SEM Analysis
Sample Preparation for TEM Analysis
Tensile Testing
Ex-situ Residual Strain and Stress Measurements
Optimization of Engine Block Heat Treatment Parameters
Replication of Engine Block Cylinder Microstructure
Variation of Solution Heat Treatment Parameters
In-situ/Ex-situ Residual Strain and Stress Analysis
Investigated Solution Heat Treatment Parameters
Engine Block Heating
In-situ Residual Strain Mapping
Ex-situ Residual Stress Mapping Following T4 Treatment
CFD Heat Transfer Modelling of Quenching Process
Numerical Solution Technique of Governing Equations
Model Parameters and Boundary Conditions
Chapter 4: Determining the Mechanism of Cylinder Distortion
Analysis of Macro-Distortion
Microstructural Analysis of Cylinder Bridge
Dendritic Structure
Secondary Phases in Interdendritic Regions Distortion in heat treatable
Precipitates in Aluminum Dendrites
Residual Strain and Stress Mapping
Aluminum Cylinder Bridge
Gray Cast Iron Cylinder Liners
Effect of Phase Transformation on Distortion
Effect of Microstructure, Mechanical Properties and Residual Stress on Distortion
Chapter 5: Optimization of Solution Heat Treatment Process
Microstructure and Mechanical Properties
Replication of Cylinder Bridge Microstructure using Billet Castings
Billet Casting and Cylinder Bridge Dendritic Structure
Eutectic Si
Morphology of the Al-Cu and Al-Fe-Mn-Si Intermetallics
Volume Fraction of the Al-Cu and Al-Fe-Mn-Si Intermetallics
Porosity
Tensile Properties of Replicating Billets
Fractography
Solution Heat Treatment of Replicating Billet Castings
SHT Temperature
SHT Temperatures
Analysis of Incipient Melting using Differential Scanning Calorimetry
Residual Stress/Strain Analysis
In-situ analysis of d0 during SHT
Microstructure
Composition of α-Al Dendrites
Effect of Thermal Expansion on d0 Spacing
Variation in d0 Spacing during SHT
In-situ Residual Strain Analysis during SHT
Residual Strain Relief during Elevated Temperature Soaking
Residual Strain Development during Cooling
Ex-situ Residual Stress Analysis
Residual Stress Prior to In-situ SHT
Residual Stress Following In-situ SHT
Optimal Solution Heat Treatment Schedule
Chapter 6: Conclusions
Optimization of Heat Treatment Parameters
Contributions of Dissertation
Chapter 7: Recommendations for Future Work
Heat Transfer Simulation of Engine Heat-up
Heat Treatment Temperature Profile
Peer-Reviewed Journal Publications
Conference Proceedings
Conference Presentations
Findings
Scholarships, Awards and Fellowships
Full Text
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