Mitigation Mechanism of Membrane Fouling in MnFeOx Functionalized Ceramic Membrane Catalyzed Ozonation Process for Treating Natural Surface Water

Abstract

In order to efficiently remove NOMs in natural surface water and alleviate membrane pollution at the same time, a flat microfiltration ceramic membrane (CM) was modified with MnFeOX (Mn-Fe-CM), and a coagulation–precipitation–sand filtration pretreatment coupled with an in situ ozonation-ceramic membrane filtration system (Pretreatment/O3/Mn-Fe-CM) was constructed for this study. The results show that the removal rates of dissolved organic carbon (DOC), specific ultraviolet absorption (SUVA) and NH4+-N by the Pretreatment/O3/Mn-Fe-CM system were 51.1%, 67.9% and 65.71%, respectively. Macromolecular organic compounds such as aromatic proteins and soluble microbial products (SMPs) were also effectively removed. The working time of the membrane was about twice that in the Pretreatment/CM system without the in situ ozone oxidation, which was measured by the change in transmembrane pressure, proving that membrane fouling was significantly reduced. Finally, based on the SEM, AFM and other characterization results, it was concluded that the main mitigation mechanisms of membrane fouling in the Pretreatment/O3/Mn-Fe-CM system was as follows: (1) pretreatment could remove part of DOC and SUVA to reduce their subsequent entrapment on a membrane surface; (2) a certain amount of shear force generated by O3 aeration can reduce the adhesion of pollutants; (3) the loaded MnFeOX with a higher catalytic ability produced a smoother active layer on the surface of the ceramic membrane, which was conducive in reducing the contact among Mn-Fe-CM, O3 and pollutants, thus increasing the proportion of reversible pollution and further reducing the adhesion of pollutants; (4) Mn-Fe-CM catalyzed O3 to produce ·OH to degrade the pollutants adsorbed on the membrane surface into smaller molecular organic matter, which enabled them pass through the membrane pores, reducing their accumulation on the membrane surface.