Abstract
The miscibility behaviour of poly(chloromethyl methacrylate) (PCMMA) and poly(2-chloroethyl methacrylate) (PCEMA) with poly(ε-caprolactone) (PCL) was investigated by differential scanning calorimetry. Each of these blends exhibited a single composition-dependent glass transition temperature indicative of miscibility. Based on the melting point depression of PCL in the blends, the interaction parameters were found to be −0.82 and −0.76 for PCMMA/PCL and PCEMA/PCL blends respectively.
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