Abstract

Miscibility experimental results are confronted to current predictive methods, and possible causes for the discrepancy between predicted and observed behavior are discussed. A correlation between miscibility and the number of atoms forming hydrogen bonds per the number of non-hydrogen atoms in the repeat unit of the polymers has been noted. Molecular modeling has been used for the first time to investigate the formation of interchain hydrogen bonds in the blends and is proposed as an aid for the study of miscibility in systems where strong hydrogen bonds occur

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