Mineralogy, alteration, and sulfur isotope geochemistry of the Zehabad intermediate-sulfidation epithermal deposit, NW Iran

Abstract

The Zehabad Pb-Zn-Au-Ag (Cu) deposit lies in the Alborz magmatic arc of northwestern Iran. Ore-bearing breccia veins hosted by Eocene tuffs emplaced along the 80?130° trending fault and fracture zone. Mineralization occurs in the contact of the late Eocene igneous bodies and the Eocene volcanic and volcanosedimentary Karaj Formation. Mineralization formed in five stages: 1) disseminated framboidal pyrite and minor chalcopyrite and sphalerite; 2) quartz veins containing chalcopyrite, bornite, pyrite, and sphalerite; 3) deposition of specularite and gold grains hosted in quartz veins that crosscut chalcopyrite; 4) the main stage of mineralization that contains galena, sphalerite, tennantite-tetrahedrite, pyrite, sulfosalts, and gold; 5) barren quartz-calcite veins with sulfide mineral fragments of earlier stages. The hydrothermal alteration from closest to the veins outwards includes: a) silicification; b) phyllic with quartz, pyrite, sericite, and calcite; c) argillic with illite, kaolinite, and montmorillonite; d) propylitic containing epidote, calcite, chlorite, and sericite and; e) carbonatization that crosscuts all previous alteration types. Quartz and calcite are the most important gangue minerals at the deposit and show a close relationship with mineralization. Sulfur isotope compositions (0.8‰ to -10.1‰) suggest that the ore-forming fluids derived from magmatic sources with a temperature range of 276-288 °C. According to the field (macroscopic), microscopic, alteration, and sulfur isotope studies, the Zehabad base and precious metal mineralization is considered an intermediate-sulfidation epithermal deposit.