Abstract
The infrared absorption spectrum of BrCN has been recorded in the reǵion 325–4720 cm−1 with a Bruker 120 HR interferometer. More than 30 000 lines have been measured and most of them have been assigned: 10734 lines for 151 bands and 10993 lines for 150 bands of 79Br12C14N and 81Br12C14N, respectively. Also new millimetre-wave spectra were measured for the vibrational excited states lying between 1000 cm−1 and 1400 cm-′. After a band by band analysis of these transitions, rovibrational global analyses have been performed for both isotopomers using all available experimental data. The rotational I-type resonance and the anharmonic resonance associated with kl22 are taken into account in one-step diagonalization procedures. Sets of 73 molecular parameters are obtained for both isotopomers. It is shown that the existing equilibrium structure is likely to be reliable. The vibrational dependence of the quartic centrifugal distortion constant is analysed for the linear triatomic molecules studied so far.
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