Abstract
The millimeter-wave spectrum of HCCCCF was observed in the ground state as well as in the low-lying vibrationally excited states ν7, ν8, ν9and also associated ν8+ ν9, 2ν9, and 3ν9states. The HCCCCF molecule was produced by a dc glow discharge in a flowing vapor of 2,3,4,5,6-pentafluorostyrene. Thel-type doubling constants determined are in good agreement with the values predicted from the harmonic force field calculation.
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