Abstract

Gas-phase spectra of four isotopic species of GaBr have been detected in the millimeter wavelength region. The molecules were produced by a flame reaction of gallium and bromine at 1000° C. From the rotational spectra molecular constants have been determined for 69Ga 79Br, 69Ga 81Br, 71Ga 79Br, 71Ga 81Br. The equilibrium internuclear distance is r e = 2.3524907(82).

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