Milli-Watt Power Harvesting from Dual Triboelectric and Piezoelectric Effects of Multifunctional Green and Robust Reduced Graphene Oxide/P(VDF-TrFE) Composite Flexible Films.

Abstract

For a variety of mechanical energy harvesting as well as biomedical device applications, flexible energy devices are useful which require the development of environment-friendly and robust materials and devices. In this manuscript, we demonstrate a lead-free, facile, low-cost, sol-gel-processed reduced graphene oxide (rGO)/P(VDF-TrFE) nanocomposite with multipurpose capability demonstration as a piezoelectric nanogenerator (PENG) and hybrid piezoelectric triboelectric nanogenerator (HPTENG) devices. The structural analysis of the materials shows that the interactions between the rGO and P(VDF-TrFE) matrix help in breaking the centrosymmetry of rGO, resulting in a strong enhancement in the piezoelectric, ferroelectric, and triboelectric properties of composites over pristine P(VDF-TrFE) films. In the case of PENG, the composite devices showed >22 times improvement in the piezoelectric output voltage over the pristine P(VDF-TrFE) PENG device with the highest output voltage of 89.7 V for the 0.5 wt % rGO composite. Also, HPTENG devices based on composite films generated an average VOC of 227 V, much higher than the pristine P(VDF-TrFE)-based devices. Maximum output power densities measured were 0.28 W/cm3 and 0.34 mW/cm3 for hybrid piezoelectric-triboelectric and piezoelectric devices, respectively. The triboelectric devices demonstrated lighting of 45 blue light-emitting diodes directly, connected in series, by harvesting mechanical energy generated by repeated finger tapping. The study highlights the promise of rGO/P(VDF-TrFE) composites for PENG and HPTENG devices with dramatically improved electrical output.