Abstract

Sludge pre-treatments are emerging as part of the disposal process of solid by-products of wastewater purification. One of their benefits is the increase in methane production rate and/or yield, along with higher loading capacities of existing digesters. In this study, we report the performance of a pilot-scale compartmentalized digester (volume of 18.6 m3) that utilized a mild thermal pre-treatment at 70 °C coupled with hydrogen peroxide dosing. Compared with a reference conventional anaerobic digester, this technique allowed an increased organic loading rate from 1.4 to 4.2 kg volatile solids (VS)/(m3d) and an increment in the solids degradation from 40 to 44%. To some extent, these improvements were promoted by the solubilization of the tightly-bound fraction of the extracellular polymeric substances to looser and more accessible fractions without the formation of refractory compounds. In sum, our results suggest that this pre-treatment method could increase the treatment capacity of existing digesters without significant retrofitting.

Highlights

  • Population growth and increase in the coverage of sanitation are factors that increase the volume of waste activated sludge (WAS) to be treated

  • We examined to what extent mild thermal pre-treatment provoked an increase in the WAS hydrolysis rate, which in turn allowed a substantial increase in applicable organic loading rate (OLR) in a compartmentalized digester, combining the advantages of the two treatment approaches

  • The effects of pre-treatment temperature, exposure time, and peroxide dose on biodegradation, kCH4, sCOD, E. coli, capillary suction time (CST), and volatile solids (VS) degradation were studied in a series of three batch experiments

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Summary

A Pilot-Scale Study

Adrian Gonzalez 1, *, Hongxiao Guo 1 , Oscar Ortega-Ibáñez 2 , Coert Petri 3 , Jules B. van Lier 1 , Merle de Kreuk 1 and Alexander Hendriks 4.

Introduction
Materials and Methods
Anaerobic Digestion
Analytical Methods
Biodegradation and Methane Production Rate
Design of Experiments and Statistical Analyses
Lab-Scale Experiments
Effects of Temperature and Time
Effects of Peroxide
Reproducibility
Pilot-Scale Experiments
Effects of Mild Thermal Pre-Treatment Coupled with Hydrogen Peroxide
Oshift
Effects of Compartmentalized-Digestion and Recirculation
Microbial Composition and Structure
Dewaterability
Method
Energy Balance and Cost Implications
Conclusions
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