Abstract
ABSTRACT An optimised method was established for the determination of four chloropropanols in paper straws, namely 1,3-dichloropropan-2-ol(1,3-DCP), 2,3-dichloropropan-1-ol (2,3-DCP), 3-monochloropropane-1,2-diol (3-MCPD) and 2-monochloropropane-1,3-diol (2-MCPD). After extraction with a food simulant, purification with matrix solid phase dispersion (MSPD), and derivatisation using heptafluorobutyrylimidazole (HFBI), the chloropropanols were analysed by gas chromatography–tandem mass spectrometry (GC-MS/MS), and quantified with a deuterated internal standard. Under the optimised conditions, the limit of detection (LOD) was 0.200 µg/L for the four target compounds. The recoveries were in the range of 71.4% – 119.4% with relative standard deviations (RSDs) of 0.4% – 9.9%. The method fulfilled the requirements of the European regulations for the quantification of 3-MCPD and 1,3-DCP. Fifteen paperboard straws were tested using the proposed method. The results showed that 1,3-DCP and 3-MCPD exhibited the highest detection rate among the four chloropropanols tested (93.3%). the method can be used to detect chloropropanol contamination in paperboard products, and further to guide food manufacturers to reduce the levels of chloropropanols in paperboard food contact materials.
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