Migration of dissolved carbon on bare karst slopes in soil in response to natural rainfall events

Abstract

Soil carbon in karst critical zones is an essential part of the global carbon pool, and the migration of dissolved carbon is a vital component of the carbon cycle in such regions. The unique “dual hydrological structure” makes the path and process of migration of soil dissolved carbon driven by rainfall unclear in karst slopes, which ultimately hinders the accurate evaluation of the carbon sink effect in such regions. Therefore, based on field monitoring of natural rainfall, this study evaluated the process and characteristics of the spatial migration of soil dissolved carbon in bare karst slopes and its response to natural rainfall (rainfall duration and amount). The results showed that the concentration of dissolved carbon transported in surface runoff was significantly lower than that transported within the soil layer; however, carbon loss displayed the opposite trend. Rainfall factors (rainfall amount and duration) and runoff volume significantly affected soil dissolved carbon, contributing 46.91% to soil dissolved carbon. Rainfall factors significantly affect soil dissolved carbon migration by influencing runoff. In addition, the hydrological path is an important factor affecting soil dissolved carbon transport. Our study shows that the soil and bedrock interface (SBI) and shallow karst fissures (SKF) are the main routes of dissolved carbon migration in soils in bare karst slopes. Dissolved carbon migrating along SKF is a vital contributor to the “missing carbon sink” in karst regions, and dissolved carbon migrating along the SBI is potentially an important contributor to the “missing carbon sink.” This study provides primary data and is expected to serve as a reference for revealing the mechanism of karst carbon migration and transformation and accurately evaluating the carbon sink effect in karst areas.