Mid-Infrared Amplified Spontaneous Emission from the f′ 0g+ (1D2) Ion-Pair State and Spectroscopic Characterization of the Shallow 0g+ (ab) Valence State of I2

Abstract

In this paper, we describe amplified spontaneous emission (ASE) from the f' 0g+ (1D2) ion-pair state of I2 populated through a two-step laser excitation technique via the B 3Π(0u+) valence state. The intense infrared emission propagating in the direction of the incident laser beam is assigned to the ASE transition from the f' 0g+ (1D2) state to the F' 0u+ (1D2) ion-pair state. The subsequent ultraviolet fluorescence transition from the F' 0u+ (1D2) state to the 0g+ (bb) state as well as the 0g+ (ab) state is also reported. By Franck-Condon simulation of the cascading F' 0u+ (1D2) → 0g+ (bb) band, we determine the population distributions in the F' 0u+ (1D2) state generated by ASE, which are consistent with the intensity profile of the mid-infrared ASE spectrum. Finally, employing these vibrational distributions for the F' 0u+ (1D2) state, spectral parameters for the shallow 0g+ (ab) state are derived.