Abstract

Microwave radiation was used as the heating source in southern pine wood liquefaction with PEG/ glycerin binary solvent. It was found that microwave heat- ing was more efficient than conventional oil bath heating for wood liquefaction. The wood residue content of the H2SO4 catalyzed liquefied wood dropped to zero within 5 min with microwave heating. The resulting liquefied wood polyols have suitable hydroxyl values for the preparation of rigid PU foams. Both the compressive strength and apparent modulus of the liquefied-wood-based PU foams increased as the iso- cyanate index increased from 80 to 120. The foams from H3PO4 catalyzed polyols had lower densities than those from H2SO4 and the petroleum-based controls. They also showed lower strength and modulus than those from H2SO4. Liquefied-wood-based PU foams generally have lower com- pressive strength and apparent modulus than the petroleum- based controls. However, they showed better restorability from deformation than the petroleum-based controls.

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