Microwave synthesis of zeolite CHA (chabazite) membranes with high pervaporation performance in absence of organic structure directing agents

Abstract

Thin and compact zeolite chabazite membranes were prepared by microwave heating using symmetric stainless steel tubular supports. The microstructures (crystal size and membrane thickness) and separation performances of supported chabazite layers were strongly affected by heating method, synthesis time and synthesis temperature. The best membrane prepared by microwave heating under optimized conditions showed fluxes of 7.3 and 9.1 kg/(m2 h) and separation factors of 2000 and 2500 for 90 wt.% ethanol and isopropanol aqueous solutions at 348 K, respectively. These fluxes were twice as high as those of the chabazite membranes prepared by conventional heating due to the thinner zeolite layers and lower resistance of the support layer in the microwave heating system. The membrane prepared on the 3-time-reused stainless steel support showed comparable separation performance with the membrane on the fresh support, suggesting that the stainless steel supports had a good reuse prospect for chabazite membrane preparation. Synthesis reproducibility and hydrothermal stability of chabazite membranes by microwave heating were also investigated.