Microwave Synthesis of Spinel MgFe2O4 Nanoparticles and the Effect of Annealing on Photocatalysis.

Abstract

Through microwave heating in ethanol and with subsequent annealing, crystalline MgFe2O4 nanoparticles are produced rapidly and in high yields >99%. Under varied annealing temperatures, the degree of Mg and Fe site inversion changes the optical, electronic, and composition of the nanoparticles. A small particle size of ∼10 nm is achievable with the aid of an ammonium salt mineralizer that caps the particles during nucleation and growth. Particles with the lowest inversion parameter and limited sintering upon annealing (at 600 °C) exhibit the greatest production of hydroxyl radicals under visible light illumination. As such, these particles also facilitate the degradation of methylene blue dye faster than those particles annealed at higher temperature and show a rate constant of 0.061 h-1 for degrading 10 ppm methylene blue with 20 mg of catalyst.