Abstract
The microwave absorption spectrum of methylamine- d 1 has been investigated in the range from 20 to 110 GHz. One hundred twenty-two transitions in the ground vibrational state are least-squares-analyzed with 21 molecular parameters according to a group-theoretical formalism modified from the method developed previously for CH 3NH 2. Pure torsional and wagging energy differences are derived from the parameters obtained, and a classical tunneling path during the inversion motion of the unsymmetrical-NHD amino group is deduced by combining an assumed parametrization for the tunneling path with traditional methods for treating the internal rotation problem.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
