Abstract
The microwave spectra of three isotopic Ge species of germyl azide, GeH3N3, have been assigned. The splittings due to internal rotation of the germyl group have been analyzed yielding a threefold barrier of 86.6(1) cm−1. An electric dipole moment of 2.58(2) D has been determined from the Stark effect. The following refined structural parameters have been obtained with a fixed and slightly bent azide group: r(GeN)=1.866(12) Å, r(GeH)=1.497(8) Å, α(GeNN)=115.9(14)°, α(HGeH)=112.2(10)° and a tilt of the symmetric germyl group of 4.0° away from the azide group.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
