Abstract
The J = 3-2, 4-3, and 5-4 transitions of DCO + and the J = 3-2 and 4-3 transitions of HCO +, both in the ν 2, 2 ν 2, ν 1, and ν 3 states, were observed to derive the rotational, centrifugal distortion, and l-type doubling constants. The Fermi resonance between the ν 1 and 4 ν 2 0 states of DCO + was analyzed using the observed molecular constants of the ν 1, ν 2, and 2 ν 2 states. The effect of the discharge electric field was noticed on the ν 2 and 2 ν 2 spectra.
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