Abstract
Rotational spectra of the CO–H 2S complex were studied using a cavity Fourier transform microwave spectrometer. Altogether 16 isotopomers were investigated. The tunneling splitting due to interchange of the “bonded” and “non-bonded” hydrogen (deuterium) nuclei of the H 2S (D 2S) subunit was observed and analyzed. In addition, the nuclear quadrupole hyperfine structures due to the quadrupolar 33S and 17O nuclei could be resolved and analyzed. The resulting rotational, tunneling, and hyperfine constants were used to derive structural and dynamical information about the complex.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.