Abstract
The pyrolysis products of CH 2C(CH 3)NO ( syn form) have been determined by microwave spectroscopy. The pyrolysis products of CH 2C(CH 3)NO ( syn form) and its 15N isotopic species were found to be CH 2O, CH 3CN, and CH 3C 15N. The produce of formaldehyde and methyl cyanide suggests that the CC and NO double bonds of CH 2C(CH 3)NO ( syn form) were broken. To explain the generation of the two molecules, a four-membered ring molecule ( 9) as an intermediate, is proposed. The four-membered ring molecule as an intermediate is also supported by ab initio MO calculation. Applying the pyrolysis mechanism obtained for 2-nitrosopropene ( syn form) to that of 1,1,2-trichloronitrosoethane, one of its complicated pyrolysis mechanisms was explained. The rotational constants and geometrical parameters of two intermediates, 9 and CH 2CClNO ( 13), were obtained by ab initio MO calculation (MP2/6-31G**) to predict their microwave spectra.
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