Abstract
The microwave spectra of dichlorine monoxide (Cl 2O) in its excited vibrational states were measured in the frequency range 12–56 GHz. The Coriolis interaction between the v 1 and v 3 states was analyzed and the following equilibrium rotational constants and equilibrium structure were obtained: A e = 41 938.9(4) MHz, B e = 3704.73(4) MHz, C e = 3404.07(4) MHz, r e (OCl) = 1.695 9(1) A ̊ , and ∠ e(ClOCl) = 110.88(1)°. The off-diagonal element X ah of the nuclear quadrupole interaction constant was determined by the analysis of anomalies observed in the hyperfine splittings.
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