Abstract

The microwave spectrum of cyclopropanecarboxylic acid has been measured in the 5–15GHz region using a Flygare–Balle type, pulsed-beam Fourier-transform microwave spectrometer. These lower-frequency measurements are at a much higher resolution then the previous waveguide studies. The experimental rotational constants obtained in this study were A=7625.0432(17)MHz, B=2724.7672(8)MHz, and C=2382.0755(5)MHz. The centrifugal distortion constants determined were ΔJ=0.4010(25)kHz, ΔJK=3.04(17)kHz, ΔJ=0.0434(72)kHz, and ΔK=−11.32(24)kHz.

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