Microwave-induced structural tunability of 3D δ-MnO2 microflowers for high-performance aqueous Zn-ion batteries

Abstract

Rechargeable aqueous Zn//MnO2 batteries are the promising alternatives to lithium-ion batteries owing to their high safety, high energy density, low cost, and environmental friendliness. However, the unstable MnO2 cathode causes poor practical energy density and serious capacity fading. To overcome this issue, herein, a unique 2D nanosheets self-supported 3D δ-MnO2 microflower hierarchical architecture is rationally designed and synthesized by taking advantage of its microwave-absorbing characteristics. The 2D nanosheets with high surface area could expose numerous active sites for ions/electrons transfer. Also, the 3D assembled structure acting as building blocks would ensure structural stability for long-life cycles. Benefiting from these synergistic merits, the δ-MnO2 microflowers deliver a high capacity of 287.6 mA h g−1 at 0.5 C, an excellent rate capability of 202.7 mA h g−1 at 5 C, and a superior cycling retention of 76.5% over 1000 cycles at 10 C. Furthermore, a storage mechanism of H+/Zn2+ co-insertion accompanied by the deposition of zinc sulfate hydroxide hydrate is clarified by the aid of ex-situ XRD and SEM technologies. This work provides a new pathway for developing high capacity and long lifespan ZIBs.