Abstract

By causing the water molecule vibration to generate heat, microwave has become a rapid and efficient heating method which is widely used in industrial production. Herein, microwave heating assistant interfacial polymerization (IP) process was innovatively applied to fabricate polypiperazine-amide nanofiltration (NF) membrane for the first time. With microwave heating, a uniform and faultless polyamide (PA) layer could be generated with low monomer concentration. The pure water flux (PWF) of the NF membrane fabricated with microwave heating was 157.1 L m-2 h-1 with the Na2SO4 rejection of 97.7% under 0.6 MPa. Meanwhile, such NF membrane showed extraordinary selectivity to Cl- and SO42− for a series of mixing solution with different concentrations. This new insight into microwave heating assistant IP provides a feasible method for the high-permselectivity NF membranes fabrication.

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