Abstract
The rotational spectrum of vinylstibine was recorded by pulsed-nozzle microwave Fourier transform spectroscopy between 5 and 40 GHz. H2C12CH121SbH2, H2C12CH123SbH2, H2C13CH121SbH2 and H2C13CH123SbH2 isotopic species were observed in natural abundance and frequencies of the lines were fitted to the Hamiltonian of Watson (A reduction, Ir representation). Rotational and quartic centrifugal distortion constants and also quadrupole tensor elements and spin–rotation constants were derived for each isotopic species. An rs substitution distance for the C–Sb bond length was calculated as rs(C–Sb) = 2.13(3) Å.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
