Microwave-assisted synthesis of Zr-based metal–organic framework (Zr-fum-fcu-MOF) for gas adsorption separation

Abstract

A reliable strategy of Zr-based metal–organic framework (Zr-fum-fcu-MOF) was successfully achieved by microwave-assisted synthesis. Well-shaped and octahedral Zr-fum-fcu-MOF particles were obtained at 100 °C for 1.0 h with 150 equivalents of FA per ZrOCl2·8H2O. A clear difference for the adsorption behavior of iso-C4H10 (1.11 mmol/g) and n-C4H10 (3.56 mmol/g) was observed at 25 °C and 1.0 bar. Moreover, 3.16 mmol/g CO2 uptake was also obtained at 0 °C and 1.0 bar while the adsorption capacity of CH4 and N2 is 0.85 mmol/g and 0.21 mmol/g, respectively. This indicates that Zr-fum-fcu-MOF is a promising candidate for CO2 capture.