Abstract
Microwave-assisted synthesis method was used to prepare europium hydroxide (Eu(OH)3) and different percentages of 1, 5, and 10 % nickel-doped Eu(OH)3 (Ni–Eu(OH)3) nanorods (NRs). X-ray diffraction study showed a hexagonal phase with an average crystallite size in the range of 21 – 35 nm for Eu(OH)3 and Ni–Eu(OH)3 NRs. FT-IR and Raman studies also confirmed the synthesis of Eu(OH)3 and Ni–Eu(OH)3. The synthesized materials showed rod-like morphology with an average length and diameter between 27 – 50 nm and 8 – 13 nm, respectively. The band gap energies of Ni–Eu(OH)3 NRs were reduced (4.06 – 3.50 eV), which indicates that the doping of Ni2+ ions has influenced the band gap energy of Eu(OH)3. The PL study exhibited PL quenching with Ni doping. The photocatalytic degradation of 4-nitrophenol (4-NP) by the synthesized materials under UV light irradiation was investigated, in which 10 % Ni–Eu(OH)3 NRs showed the best response. A kinetic study was also conducted which shows pseudo-first-order kinetics. Based on this, Ni–Eu(OH)3 NRs have shown a potential to be a UV-light active material for photocatalysis.
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