Microwave assisted sol–gel synthesis of titanium dioxide using hydrochloric and acetic acid as catalysts

Abstract

Titanium dioxide (TiO2) was synthesized by microwave assisted sol–gel. The effect of the acid type used as catalyst on the phase transformation of TiO2 was investigated (hydrochloric or acetic acid). The samples obtained were characterized by scanning electron microscopy (SEM), this micrographs showed particles with irregular shapes. The results of Fourier transform-infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) showed present signals of O and Ti. When hydrochloric acid was used as catalyst, three titania polymorphs were detected by X-ray diffraction (XRD), anatase, rutile and brookite, where the crystallite size was in the range of 9 and 16nm. On the other hand, a single anatase phase was formed when acetic acid was used after only 15min of reaction time. The anatase average crystallite size was obtained between 11 and 22nm.