Abstract
Poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] is synthesized by microwave-assisted McMurry polymerization utilizing low-valent titanium generated from titanium tetrachloride and zinc. The obtained polymer is fluorescent with an average molecular weight of approximately 65,000 g/mol and a polydispersity of M w/ M n ≈ 3. Absorption and fluorescence spectroscopy in solution and on spin-cast thin films reveal that the bis-alkoxy substituted PNV has a short effective conjugation length but a quite efficient exciton migration.
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