Microtexture and magnetoresistance of glass-like carbons

Abstract

Microtextures of glass-like carbons commercially available were investigated through scanning electron microscopy and measurement of their magnetoresistance. A field-emission electron gun type SEM, which is characterized by a specimen chamber equipped in its objective lens, was operated with the acceleration voltage of 2 kV and high fidelity observations were thereby achieved with a resolving power of 2 nm. All the specimens exhibit granular microtextures with the mean grain diameter spanning 6–13 nm. The mean grain diameter correlates to the mean crystallite size L a (110) determined by the X-ray powder diffractometry. The density of each sample calculated by using the mean diameter and the X-ray parameters reproduces well its catalog value. Negative magnetoresistance was observed just for the specimens whose average grain sizes are not smaller than 7.3 nm. The crystallite size L a(110) of the specimen whose grain size shows the minimum value for appearance of negative magnetoresistance is estimated to be 2.7 nm. The absolute value of negative magnetoresistance under a constant magnetic field increases with increasing the average grain size.