Abstract
In the present paper, the microstructures of three kinds of in-situ reinforcements Al-Ti-C, Al-Ti-B, and Al-Ti-B-C-Ce were deeply investigated using a combination of scanning electron microscopy, X-ray diffraction spectroscopy, and transmission electron microscopy. The effect of in-situ reinforcements on the room temperature and elevated temperature (350 °C) tensile strengths of Al-13Si-4Cu-1Mg-2Ni alloy were analyzed. It is found that doping with trace amounts of B and Ce, the size of the Al3Ti phase in the in-situ reinforced alloy changed from 80 µm (un-reinforced) to about 10 µm, with the simultaneous formation of the AlTiCe phase. The Al-Ti-B-C-Ce reinforcement which is rapid solidified, was more effective and superior to enhance the tensile strengths of the Al-13Si-4Cu-1Mg-2Ni alloy, both at room and high temperatures than those of addition other reinforcements. The room temperature (RT) strength increased by 19.0%, and the 350 °C-strength increased by 18.4%.
Highlights
In last two decades, in situ metal matrix composites, as a branch of discontinuous reinforced metal matrix composites, have been attracting many researchers interest and have made notable achievements [1]
B4 C powder wrapped in aluminum foil at 800 ◦ C, was placed in a melting crucible to prepare Al-Ti-B-C intermediate alloy
Three different kinds of reinforcements Al-Ti-C, Al-Ti-B, and Al-Ti-B-C-Ce were added to the alloy Al-13Si-4Cu-1Mg-2Ni, to compare its strengthening effect
Summary
In situ metal matrix composites, as a branch of discontinuous reinforced metal matrix composites, have been attracting many researchers interest and have made notable achievements [1]. It is of great importance to conduct more in-depth research on in situ metal matrix composites, for applications in leading-edge manufacturing and innovation areas, such as alloy material design theory, amorphous nano-crystalline matrix inoculation and refinement mechanism, and ceramic nano-particulate reinforcement. TiC particles, as the reinforced phase of in-situ aluminum matrix composites, show many excellent properties: high hardness, high melting point, high elastic modulus, low thermal conductivity, and good wettability and thermodynamic stability in molten aluminum [15]. Al-13Si-4Cu-1Mg-2Ni alloy, is a widely used piston aluminum alloy through the enhanced in-situ method which further improves its mechanical properties This is of great significance in meeting the research and development needs of high performance engines, such as high-power density diesel engines. Accumulation of TiB2 can impair the quality “Poisoning” by Zr, Cr, and Mn can lead to failure
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