Abstract

In the present paper, the microstructures of three kinds of in-situ reinforcements Al-Ti-C, Al-Ti-B, and Al-Ti-B-C-Ce were deeply investigated using a combination of scanning electron microscopy, X-ray diffraction spectroscopy, and transmission electron microscopy. The effect of in-situ reinforcements on the room temperature and elevated temperature (350 °C) tensile strengths of Al-13Si-4Cu-1Mg-2Ni alloy were analyzed. It is found that doping with trace amounts of B and Ce, the size of the Al3Ti phase in the in-situ reinforced alloy changed from 80 µm (un-reinforced) to about 10 µm, with the simultaneous formation of the AlTiCe phase. The Al-Ti-B-C-Ce reinforcement which is rapid solidified, was more effective and superior to enhance the tensile strengths of the Al-13Si-4Cu-1Mg-2Ni alloy, both at room and high temperatures than those of addition other reinforcements. The room temperature (RT) strength increased by 19.0%, and the 350 °C-strength increased by 18.4%.

Highlights

  • In last two decades, in situ metal matrix composites, as a branch of discontinuous reinforced metal matrix composites, have been attracting many researchers interest and have made notable achievements [1]

  • B4 C powder wrapped in aluminum foil at 800 ◦ C, was placed in a melting crucible to prepare Al-Ti-B-C intermediate alloy

  • Three different kinds of reinforcements Al-Ti-C, Al-Ti-B, and Al-Ti-B-C-Ce were added to the alloy Al-13Si-4Cu-1Mg-2Ni, to compare its strengthening effect

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Summary

Introduction

In situ metal matrix composites, as a branch of discontinuous reinforced metal matrix composites, have been attracting many researchers interest and have made notable achievements [1]. It is of great importance to conduct more in-depth research on in situ metal matrix composites, for applications in leading-edge manufacturing and innovation areas, such as alloy material design theory, amorphous nano-crystalline matrix inoculation and refinement mechanism, and ceramic nano-particulate reinforcement. TiC particles, as the reinforced phase of in-situ aluminum matrix composites, show many excellent properties: high hardness, high melting point, high elastic modulus, low thermal conductivity, and good wettability and thermodynamic stability in molten aluminum [15]. Al-13Si-4Cu-1Mg-2Ni alloy, is a widely used piston aluminum alloy through the enhanced in-situ method which further improves its mechanical properties This is of great significance in meeting the research and development needs of high performance engines, such as high-power density diesel engines. Accumulation of TiB2 can impair the quality “Poisoning” by Zr, Cr, and Mn can lead to failure

Intermediate Alloy Preparation
The Process of Matrix Alloy
The Process of Composite Alloys
The Microstructure Analysis
The Mechanical Tensile Tests
X-ray Diffraction Analysis
TEM Analysis
SEM Analysis
XRD Analysis
Effects
Strengthening Mechanism
Conclusions
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